| Overview |
| Instructions |
| Operating scheme |
| Substances |
| Equipment |
| Evaluation |
| Analytics |
| - 1H-NMR |
| - 13C-NMR |
| - IR |
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; Side reactions |
1H-NMR |
| 1H-NMR: crude product | |||
| 300 MHz, MeOD | |||
| delta [ppm] | mult. | atoms | assignment |
| 1.42 | m | 1 H | 3-H (quinuclidine) |
| 1.89 | m | 1 H | 4-H (quinuclidine) |
| 2.07 | m | 1 H | 3-H (quinuclidine) |
| 2.26 | m | 2 H | 8-H (quinuclidine) |
| 2.75 | m | 1 H | 5-H (quinuclidine) |
| 3.40 | m | 1 H | 7-H (quinuclidine) |
| 3.49 | dd | 1 H | 6-H (quinuclidine) |
| 3.69 | m | 1 H | 6-H (quinuclidine) |
| 4.04 | m | 1 H | 2-H (quinuclidine) |
| 4.49 | m | 1 H | 6-H (quinuclidine) |
| 4.83 | s | 1 H | O-H |
| 5.0 | m | 1 H | =CH2 |
| 5.04 | d | 1 H | CH2 benzyl |
| 5.15 | m | 1 H | =CH2 |
| 5.24 | d | 1 H | CH2 benzyl |
| 5.70 | m | 1 H | C=CH- |
| 6.68 | m | 1 H | -CH-OH |
| 7.59 | m | 3 H | 3'-H, 4'-H, 5'-H (phenyl) |
| 7.76 | m | 3 H | 6-H (quinoline), 2'-H, 6'-H (phenyl) |
| 7.84 | m | 1 H | 7-H (quinoline) |
| 7.97 | d | 1 H | 3-H (quinoline) |
| 8.12 | d | 1 H | 8-H (quinoline) |
| 8.29 | d | 1 H | 5-H (quinoline) |
| 8.95 | d | 1 H | 2-H (quinoline) |
| 1H-NMR: (-)-N-Benzylcinchonidinium chloride | |||
| 300 MHz, MeOD | |||
| delta [ppm] | mult. | atoms | assignment |
| 1.42 | m | 1 H | 3-H (quinuclidine) |
| 1.89 | m | 1 H | 4-H (quinuclidine) |
| 2.07 | m | 1 H | 3-H (quinuclidine) |
| 2.26 | m | 2 H | 8-H (quinuclidine) |
| 2.75 | m | 1 H | 5-H (quinuclidine) |
| 3.40 | m | 1 H | 7-H (quinuclidine) |
| 3.49 | m | 1 H | 6-H (quinuclidine) |
| 3.69 | m | 1 H | 6-H (quinuclidine) |
| 4.04 | m | 1 H | 2-H (quinuclidine) |
| 4.49 | m | 1 H | 6-H (quinuclidine) |
| 4.83 | s | 1 H | O-H |
| 5.0 | m | 1 H | =CH2 |
| 5.04 | d | 1 H | CH2 benzyl |
| 5.15 | m | 1 H | =CH2 |
| 5.24 | d | 1 H | CH2 benzyl |
| 5.70 | m | 1 H | C=CH- |
| 6.68 | m | 1 H | -CH-OH |
| 7.59 | m | 3 H | 3'-H, 4'-H, 5'-H (phenyl) |
| 7.76 | m | 3 H | 6-H (quinoline), 2'-H, 6'-H (phenyl) |
| 7.84 | m | 1 H | 7-H (quinoline) |
| 7.97 | d | 1 H | 3-H (quinoline) |
| 8.12 | d | 1 H | 8-H (quinoline) |
| 8.29 | d | 1 H | 5-H (quinoline) |
| 8.95 | d | 1 H | 2-H (quinoline) |